Rutile

Rutile is a common accessory mineral in high-temperature and high-pressure metamorphic rocks and in igneous rocks. Thermodynamically, rutile is the most stable polymorph of TiO2 at all temperatures, exhibiting lower total free energy than metastable phases of anatase or brookite. Consequently, the transformation of the metastable TiO2 polymorphs to rutile is irreversible. As it has the lowest molecular volume of the three main polymorphs, it is generally the primary titanium bearing phase in most high-pressure metamorphic rocks, chiefly eclogites. Within the igneous environment, rutile is a common accessory mineral in plutonic igneous rocks, though it is also found occasionally in extrusive igneous rocks, particularly those such as kimberlites and lamproites that have deep mantle sources. Anatase and brookite are found in the igneous environment particularly as products of autogenic alteration during the cooling of plutonic rocks; anatase is also found in placer deposits sourced from primary rutile. The occurrence of large specimen crystals is most common in pegmatites, skarns, and granite greisens. Rutile is found as an accessory mineral in some altered igneous rocks, and in certain gneisses and schists. In groups of acicular crystals it is frequently seen penetrating quartz as in the fléches d'amour from Graubünden, Switzerland. In 2005 the Republic of Sierra Leone in West Africa had a production capacity of 23% of the world's annual rutile supply, which rose to approximately 30% in 2008.

Rutile has a tetragonal unit cell, with unit cell parameters a = b = 4.584 Å, and c = 2.953 Å. The titanium cations have a coordination number of 6, meaning they are surrounded by an octahedron of 6 oxygen atoms. The oxygen anions have a coordination number of 3, resulting in a trigonal planar coordination. Rutile also shows a screw axis when its octahedra are viewed sequentially. Rutile crystals are most commonly observed to exhibit a prismatic or acicular growth habit with preferential orientation along their c axis, the [001] direction. This growth habit is favored as the {110} facets of rutile exhibit the lowest surface free energy and are therefore thermodynamically most stable. The c-axis oriented growth of rutile appears clearly in nanorods, nanowires and abnormal grain growth phenomena of this phase.

Rutile is commonly used to create white pigment that can then be used in paint or ceramic glazes. It is also an ore for the metal titanium, which is used in a variety of ways, including as jewelry, metal prosthetics, scissors, and surgical tools. Quartz with rutile inclusions makes for a popular gemstone.

Rutile is believed to be a powerful healing stone. It works on all of the chakras, aligning and activating each one. It is said to remove negative forces and replenish the body with positive energy. It is believed that it can enhance one's mental clarity and bring about greater achievements.