Krut'aite forms through hydrothermal processes and is often associated with clausthalite, eskebornite, berzelianite, uraninite, hematite, ferroselite, bukovite, umangite, chalcopyrite and goethite. It forms a solid solution series with trogtalite. It was first identified in Petrovice, Okres Žďár nad Sázavou, Czech Republic, which is the only known locality in the Czech republic for the mineral, but it has since been identified in other places in the world. Notable is the El Dragón Mine, Antonio Quijarro Province, Bolivia, where crystals up to a millimeter in size have been found. Other localities include: Weintraube Mine, Lerbach, Rosenhof veins, Clausthal-Zellerfeld, Harz, Lower Saxony, Germany. Tumiñico Mine, Sierra de Cacho, Villa Castelli, General La Madrid department, La Rioja, Argentina. Yutangba Selenium deposit, Enshi Co., Enshi Tujia and Miao Autonomous Prefecture (E'xi Autonomous Prefecture), Hubei Province, China.